Thermodynamic Stability of Transition States in Nanosystems
نویسندگان
چکیده
منابع مشابه
Thermodynamic Stability of Transition States in Nanosystems
We present a theory which shows that, in a closed system of fixed volume capable of undergoing a phase transition, the transition state can be thermodynamically stable against the bulk phases if a certain material parameters criterion is fulfilled. In a small system below the critical size the transition state turns into a globally stable phase that can be observed experimentally. This effect i...
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ژورنال
عنوان ژورنال: Journal of Statistical Physics
سال: 2009
ISSN: 0022-4715,1572-9613
DOI: 10.1007/s10955-009-9765-6